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Malvern Panalytical Scientific Award 2023

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Revealing the Past Without Breaking It: How XRF Preserves Ancient Masterpieces

Beneath the volcanic ash of Pompeii lies one of antiquity’s most iconic artworks—the Alexander Mosaic. This intricate floor piece, long admired for its craftsmanship, seemed to have given up all its secrets. 

Until recently…

Using advanced elemental analysis, researchers have uncovered new insights—without lifting a single tile. Through X-ray fluorescence (XRF), they’ve decoded pigment sources, material composition, and artisan techniques, all while preserving the mosaic’s integrity.

Let’s take a closer look at what was discovered—and how this same technology is transforming work across archaeology, industry, and science today.

A Masterpiece, Re-examined

Recently, scientists reanalysed the Alexander Mosaic using advanced, non-destructive techniques (Archeology News). This iconic 2,000-year-old floor mosaic, housed in Naples’ Archaeological Museum, depicts Alexander the Great’s clash with Darius of Persia.

But beyond the artistry lies a more modern story.

  • Researchers applied X-ray fluorescence (XRF) to examine the mosaic’s pigments.
  • They mapped the elemental composition of tesserae—each small tile—without removing or damaging them.
  • This analysis revealed sourcing, degradation, and artisan techniques long hidden.

This breakthrough wasn’t just a triumph for archaeologists. It showcased how modern tools can preserve history while unlocking its secrets.

Seeing Beneath the Surface with XRF

XRF works by directing X-rays at a material and measuring the fluorescent energy released by its elements. Each element responds uniquely, creating a precise elemental fingerprint.

That’s why XRF is ideal for:

  • Pigment analysis in art and artifacts.
  • Material identification in heritage objects.
  • On-site evaluation without sampling or destruction.

With XRF, researchers could “see” what was once invisible—the chemistry of antiquity, preserved in every tile.

XRF at the Heart of Field Discovery

Portable Analytical Solutions (PAS) offers leading XRF technologies that allow researchers and professionals to take the lab with them—into the field, the gallery, or the conservation lab.

Here’s how XRF supports critical sectors:

Cultural Heritage & Archaeology

  • Non-invasive pigment analysis of mosaics, paintings, ceramics, and metalwork.
  • Verification of authenticity through elemental signatures.
  • Monitoring of restoration materials and environmental effects.

With XRF, conservators can:

  • Detects forgeries without removing varnish or layers.
  • Monitor degradation from pollutants or light.
  • Guide restoration using data, not guesswork.

Mining & Geochemistry

  • On-site elemental analysis of ores and minerals.
  • Grade control, pathfinding, and ore identification.
  • Reduction in turnaround times from lab to decision.

XRF is used by geologists to:

  • Determine economic value in real time.
  • Trace alteration zones and lithological boundaries.
  • Map multi-element distributions across sites.

Environmental & Agricultural Applications

  • Identify heavy metal contamination in soils.
  • Screen for pollutants in water or sediment.
  • Assess fertiliser residues and elemental imbalances.

Rapid, reliable, and repeatable—XRF empowers smarter interventions when the environment is at risk.

Forensics & Industrial Safety

  • Screen unknown substances on-site.
  • Detects lead, arsenic, or hazardous alloys.
  • Investigate residues in fire scenes or crime labs.

All without opening a sample bag.

Insight: As technology continues to unmask the secrets of the past, this piece from AVEVA explores how machine learning is reshaping the field of forgery detection—bringing unprecedented precision to the art of authentication.

The Value of Non-Destructive Insight

Preservation demands care. In archaeology, you often get just one chance to understand an artifact—so non-destructive analysis is the only acceptable path.

XRF delivers just that. No slicing, no grinding—just a beam of light and a stream of data.

It’s how scientists uncovered the mosaic’s pigment story.

It’s how museums monitor their collections.

It’s how industries make confident, fast decisions.

The XRF Revolution in Your Hand

Once limited to labs, XRF is now portable, fast, and robust—ready to work in deserts, dig sites, and disaster zones.

Today’s field-ready XRF devices are:

  • Battery-operated and lightweight.
  • Rugged for tough environments.
  • Delivering lab-quality results on-site.

PAS brings these tools to those who need them—helping archaeologists, geologists, and engineers turn uncertainty into insight.

Insight: Field-based analysis demands fast, accurate insights in real time—making portable analysers essential across industries. These tools enable non-destructive, on-site testing without lab delays (Royal Society of Chemistry). Learn more about field-based analysis here

A Future Where History is Respected and Revealed

From ancient mosaics to mineral-rich landscapes, the ability to analyse without altering is reshaping how we engage with the material world. The story of the Alexander Mosaic reminds us that the past—and indeed the present—holds more than meets the eye.

XRF enables us to access that deeper understanding—not by disturbing the surface, but by reading the elemental signatures beneath it. It’s a shift toward more informed, respectful, and agile decision-making across disciplines.

If you’re exploring how XRF could enhance your work—whether in conservation, industry, or research—we’re here to help you take that next step—get in touch today.

Sources: Archaeology News ; AVEVA ; Safety Culture